Web of Spider-Man #059 (1985 Series)

Doom sends Titania out after Spidey as part of the new bad guys' arrangement to fight each others' enemies. She had previously been humiliated in defeat by Spider-Man during the Beyonder's Secret Wars. Meanwhile, at the Bugle, new owner Thomas Fireheart is speaking to all the staff. He tells them the paper is going to be more neutral over the Spider-Man reporting.Shortly after, Titania rips up part of the building looking for Spidey. Fireheart changes into Puma (out of sight of the staff). He goes after Titania but is thrown out of the window. Spidey saves him, then squares up to Titania. He gets knocked off, falling 30 storeys.With his new powers, he is fine though and is more surprised himself. Puma tries to help but is again overpowered. Spidey doesn't really want to hurt Titania...